The Signal Path shows that you are using the System Mixer, which is why the conversion takes place.
You need to select Exclusive Mode under Roon Settings → Audio. Please refer to these guides. For a Mac, this means enabling and using the Core Audio device of your Mac Mini.
As mjw correctly explained, the System Mixer is converting your DSD signal before it reaches the DAC. Enabling Exclusive Mode will bypass the mixer and allow Roon to send the native DSD stream directly to your PS Audio DAC.