Roon Server and NAS not connecting [Solved]

You don’t. If you’re able to browse the NAS in Finder, you should be able to just add the address, log in, and password in Roon.

Can you tell us a little more about your setup?

How are you browsing the NAS in Finder? What are you entering in Roon? Does the address you’re entering in Roon work in Finder if you enter it under Go > Connect To Server?