Hi, @tahsu.
I’ll share a few thoughts in response to your message.
I use an RS1221+, which is a quad-core Ryzen device. Please consider this when thinking through your plans - the 1522+ you’re considering is a reasonably powered device but it probably won’t perform as well with multi-application workloads as the RS1221+.
You mention that you’re considering promoting your NAS to primary and demoting your NUC to secondary. Personally, I think would be wise. As you point out, your NAS does data scrubbing, probably has redundancy in one form or another, and is the source of your C2 backups. To me, that sounds primary. Whether or not this changes your ripping workflow is another matter, but I think it would helpful for you to at least conceptualize the NAS as your primary.
A quick aside - I really like C2 as a Hyper Backup destination. Sounds like you do, too. I’ve used Hyper Backup with AWS and Azure in the past - C2 is so much easier to set up and use. It’s now at the top of my list of what I recommend to friends and colleagues.
FreeFileSync is great, you know what you’re doing with it, and you have an established workflow. If you’re interested in a syncing alternative, you could take a look at Syncthing (https://syncthing.net). I run Syncthing as a Synology package, though if I were to start again, I might run it in Docker. I have used many, many sync strategies over the years and Syncthing is, by far, my favorite.
You could easily set Syncthing up on both your NAS and your NUC and configure it to sync either bi-directionally or uni-directionally. In sync terms, this is equivalent to saying multi-master or single-master. You are currently bi-directional, or multi-master. For the sort of thing you’re doing, I personally prefer single master. If you were to go this route, you’d rip CDs on, lets say, your local Mac/PC/whatever. You’d use Easy Tag or whatever to modify metadata. You’d then copy those files to your NAS (personally, I just mount the Music drive from my NAS using SMB and manually drag ripped files into my Music share). That’s your primary copy, now. Then Syncthing would automatically copy them over to your NUC with no intervention from you.
I prefer Syncthing to Synology’s syncing tools. I have Syncthing “Folders” set up on my NAS for each of my home users. And my wife and I have a shared docs folder we call “Cabinet”. I have Syncthing on all of our personal computers and that’s what syncs stuff around. More on this if you want it.
I run Roon in a Docker container on Synology. It works great. There is a caveat here which is that the owner of the Docker image most (all?) of us use recently upgraded the image to the latest version of Debian slim (Bookworm) and that version is using quite a bit more memory than the previous version did. I’ve gone back to the previous version for the time being.
I also, as you aspire to do, run a few other things on my NAS including PiHole, Scrypted, glances, udp-proxy-2020, nginx, homepage, etc. My network is segmented into vlans for the purpose of isolating my personal machines from IoT stuff (and even Roon stuff). Some folks with similar setups on this forum figured out how to get Roon to run on an isolated vlan in Docker on Synology. If this is interesting to you, you can search for the thread or I can point you at it.
I suppose all of this is a long-winded way to say that I think it’s possible to consolidate to the NAS as you envision - it’s what I’ve done and I’ve now got a couple of decommissioned boxes (including a NUC) sitting around looking for something to do.
I hope some of this helps. Good luck with this … it’s fun stuff!