No, Roon tells you the source and the reason but not the individual file names. Here is the list:
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Source for the first check box: files that have been deleted via Roon, deleted from the file system, or removed from a streaming service.
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Source for the second check box: files unavailable from a storage location that no longer exists.
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Source for the third checkbox: files unavailable because the storage location or account they are associate with are disabled.
It seems what you want is for Roon to monitor your library and be able to report back when any files are removed or made unavailable for any reason and you want a detailed list of said files. I would love to hear how this could be implemented with an appropriate UI for all customers to understand and use.
Like I said, what you want will increase support enquires. It will also increase the UI complexity and take away from coding resources that could be utilized to make Roon better for everyone, not just those that want to see what files may have gone missing…or not.