I never use volume control in Roon. I prefer to do volume control at the hardware level.
Roon can playback high resolution music files. Whether someone notices a difference depends on the source and its particular mastering, the DAC, the speakers, the amp, the room treatments, etc. And even then, your personal hearing. The best high resolution I’ve heard is not available via streaming but I won’t muddy the water, so to speak. On streaming, try the albums from 2L, they are well recorded and mastered.
The only “Hi Rez” material on Tidal is MQA. If you have the appropriate subscription, you can stream the MQA files and Roon will do the first unfold on them. Qobuz, if you have access to the service, will stream high resolution flac. Note, that not everything on either service is available in high resolution. Either way Roon can play the high resolution stream. Assuming your network and internet is up to the task.
I am not sure what 2 Qb’s refer to, but if you do not have that many CDs and are going to basically stream; then, it sounds like the Nucleus will work for you.
Well, you will need to use your computer for some things. For example, if you have storage on the Nucleus, you will need a computer to copy files to it. Just keep in mind, that the Nucleus is a computer.
Your Unity Core can be used to rip CDs. When you setup Roon, you will point Roon to the Unity as a storage device only. There are several threads on here on how to do this. It will require knowledge of network path names to implement.
When it comes to this, everything should be wired except for a tablet you might use to control the RoonServer. WiFi should not be used along the path from music storage to RoonServer to Music Output.