While it is correct that R/2R architecture is intrinsically PCM there are DACs which use separate boards for DSD and do not convert to PCM (unless set that way). Examples are the Holo Audio Spring/May and the T+A DACs.
This thread sets out Jussi’s recommendations for bit depth with R/2R DACs:
I like the LNS15 Dither for upsampling PCM but try them out on your system and see what suits you.