I’ve used ReadyNAS before they were bought by Netgear, now that was equiopment built like a tank, still have one around. And later a ReadyNAS Pro. Thinking about a new one sometime in '16.
I’ve found a workaround that is working 100% every time, even after reboot.
Can you just confirm its OK using this method?
I have used Finder-Go-Connect To Server but instead of using smb or cifs I tried ftp.
This worked instantly and loaded my Nas.
I was next able to add the share through Roon’s storage menu and it added my library successfully.
I then added the drive to my start up items in my profile.
After reboot the drive loaded instantly and my library was still there in Roon.
I’ve rebooted about 10 times just to make sure its permanent and it’s loaded every time.